When the end user attempts to open a word document using Microsoft Word Online with Sharepoint 2013 using core access, the following error message will appear:
Certificate Error
The application experienced an internal error loading the SSL libraries.
When examining the url's via fiddler or httpwatch, the following url structure will occur:
https://XXX.XXXX/Shared%20Documents/Sampledoc.docx
This is incorrectly rewritten and will cause the document load to fail.